\u4e01\u57fa\u786b\u9187\u9521\uff08Butylmercaptostannane\uff09\uff0c\u5316\u5b66\u5f0fC4H10OSSn\uff0c\u662f\u4e00\u79cd\u5e38\u7528\u7684\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u4e3b\u8981\u7528\u4e8e\u805a\u6c2f\u4e59\u70ef\uff08PVC\uff09\u7684\u7a33\u5b9a\u5242\uff0c\u56e0\u5176\u4f18\u79c0\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u900f\u660e\u6027\u800c\u53d7\u5230\u9752\u7750\u3002\u4e0b\u9762\u5c06\u63a2\u8ba8\u51e0\u79cd\u4e01\u57fa\u786b\u9187\u9521\u7684\u5178\u578b\u5408\u6210\u65b9\u6cd5\u53ca\u5176\u5de5\u827a\u6d41\u7a0b\u3002<\/p>\n
\u8fd9\u662f\u5408\u6210\u4e01\u57fa\u786b\u9187\u9521\u5e38\u89c1\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u4e01\u57fa\u6c2f\u5316\u9521\uff08BuSnCl3\uff09\u4f5c\u4e3a\u8d77\u59cb\u539f\u6599\uff0c\u4e0e\u4e01\u57fa\u786b\u9187\uff08BuSH\uff09\u5728\u9002\u5f53\u7684\u6eb6\u5242\u548c\u6e29\u5ea6\u4e0b\u8fdb\u884c\u53cd\u5e94\uff0c\u751f\u6210\u4e01\u57fa\u786b\u9187\u9521\u3002\u8be5\u53cd\u5e94\u53ef\u4ee5\u8868\u793a\u4e3a\uff1a<\/p>\n
BuSnCl3+BuSH\u2192Bu2SnS+3HCl<\/span>BuSnCl<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>BuSH<\/span><\/span>\u2192<\/span><\/span>Bu<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>SnS<\/span><\/span>+<\/span><\/span>3<\/span>HCl<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n
\u53e6\u4e00\u79cd\u5408\u6210\u9014\u5f84\u662f\u5229\u7528\u4e01\u57fa\u9521\u9187\uff08Bu2SnOH\uff09\u4e0e\u786b\u5316\u6c22\uff08H2S\uff09\u53cd\u5e94\uff0c\u751f\u6210\u4e01\u57fa\u786b\u9187\u9521\u3002\u53cd\u5e94\u65b9\u7a0b\u5f0f\u5982\u4e0b\uff1a<\/p>\n
Bu2SnOH+H2S\u2192Bu2SnS+H2O<\/span>Bu<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>SnOH<\/span><\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span><\/span>\u2192<\/span><\/span>Bu<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>SnS<\/span><\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>O<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n
\u4e01\u57fa\u786b\u9187\u9521\u7684\u5408\u6210\u662f\u4e00\u4e2a\u6d89\u53ca\u591a\u6b65\u5316\u5b66\u53cd\u5e94\u7684\u8fc7\u7a0b\uff0c\u9700\u8981\u7cbe\u786e\u63a7\u5236\u53cd\u5e94\u6761\u4ef6\u548c\u5de5\u827a\u53c2\u6570\u3002\u5728\u5de5\u4e1a\u751f\u4ea7\u4e2d\uff0c\u8fd8\u9700\u8981\u8003\u8651\u6210\u672c\u6548\u76ca\u3001\u73af\u5883\u4fdd\u62a4\u548c\u5b89\u5168\u89c4\u8303\u7b49\u56e0\u7d20\uff0c\u4ee5\u5b9e\u73b0\u9ad8\u6548\u3001\u7eff\u8272\u548c\u53ef\u6301\u7eed\u7684\u751f\u4ea7\u76ee\u6807\u3002\u4e0d\u540c\u7684\u5408\u6210\u8def\u7ebf\u9002\u7528\u4e8e\u4e0d\u540c\u7684\u751f\u4ea7\u89c4\u6a21\u548c\u9700\u6c42\uff0c\u9009\u62e9\u9002\u5b9c\u7684\u5de5\u827a\u6d41\u7a0b\u662f\u6210\u529f\u7684\u5173\u952e\u3002<\/p>\n
\n
\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n
bismuth neodecanoate\/CAS 251-964-6 \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n
stannous neodecanoate catalysts \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n
DMCHA – morpholine<\/u><\/a><\/p>\n
N-Methylmorpholine – morpholine<\/u><\/a><\/p>\n
Polycat 41 catalyst CAS10294-43-5 Evonik Germany \u2013 BDMAEE<\/u><\/a><\/p>\n